Recently, I gave an "Introduction to Pd" workshop at the Puerto Rico Music Conservatory.
We covered:
Basic synthesis [osc~]
Sample playback [soundfiler]
Basic Arduino interface
Workshop materials are http://www.mediafire.com/?bgds4uykxpnlb3d (comments are in spanish)
Check out some pics http://www.epicjefferson.com/2012/05/pure-data-workshop/